Chemistry With Tanveer Kurd Mastung.

5000 Words
Chemistry - Iron Introduction Iron is the most common element found in largely in outer as well inner core of the earth. The symbol of iron is ‘Fe’ and atomic number is ‘26.’ Iron Iron is one of the earliest known elements that is being used by human beings. Salient Features of Iron Following are the major features of iron − Pure iron element is soft, ductile, and malleable. The boiling point of iron ranges between 15330C and 24500C. Iron easily gets attracted towards magnet. In dry air, iron remains inactive and does not react (with air); however, in moist air, it reacts and forms rust. Pure iron normally does not react with pure water; however, it reacts easily with ordinary of polluted water and rust forms. Iron reacts with halogen and Sulphur to form halide and sulphide accordingly. Occurrence of Iron The inner and outer cores of the earth are largely made up of iron and nickel. Most likely, iron is the most abundantly available element of the earth; however, it is the fourth most abundantly available element of the crust. Types of Iron Following are the major types iron − Hematite - Fe2O3 Magnetite - Fe3O4 Siderite - FeCO3 Compounds of Iron Following are the major compounds of iron − Iron (II) oxide - FeO Iron (III) chloride - FeCl3 Iron (III) oxide-hydroxide - Fe(OH)3 Iron (II) sulfide - FeS Iron (II) chloride - FeCl2 Iron phosphate - FePO4 Ferrate (VI) - (FeO4)2- Iron (II) acetate - Fe(C2H3O2)2 Iron (III) sulfide - Fe2S3 Iron (III) chromate - Fe2(CrO4)3 Iron (II) hydroxide - Fe(OH)2 Iron (III) acetate - C14H27Fe3O Iron (II) oxalate - FeC2O4 Iron (II) fluride - FeF2 Uses of Iron Among all the metals, iron is most widely used (about 90 percent of world’s total metal production). In most of the heavy industries, iron is the most essential element. Industries like railway, ship building, automobile, engineering construction, etc., everywhere, iron is essentially required. Chemistry - Copper Introduction Copper is a soft, ductile, and malleable metal. Copper has very high thermal and electrical conductivity. The symbol of copper is ‘Cu’ and atomic number is ’29.’ Copper Copper is known to people since (about) c. 8000 BC. Copper is the first metal, which was smelted from its ore around c. 5000 BC. Salient Features of Copper Copper was the first metal that cast into a shape (in a mold). Copper was the first metal that successful alloyed with another metal, e.g. copper alloyed with tin and resultantly bronze is prepared. It is done about c. 3500 BC. First metal to be purposefully alloyed with another metal, tin, to create bronze, c. 3500 BC. Copper has a natural reddish-orange color; it is visible once the its surface is exposed. Copper is a very good conductor of electricity and heat. Copper is an element of group 11 of the periodic table. Copper normally does not react with water; however, it does react slowly with atmospheric oxygen and form a layer of brown-black copper oxide. The brown-black copper oxide usually protects the underlying metal from further corrosion just like passivation. Passivation is a process of use of a light coat of a protective material, such as metal oxide, which is used to create a protective shell against the corrosion. Occurrence of Copper Copper is commonly found in the earth’s crust. In 1857, the largest mass of elemental copper (weighing about 420 tones) discovered. It was found on the Keweenaw Peninsula located in Michigan, US. Alloys of Copper The metal alloys, which have the copper as their major constituent, is known as copper alloys. Copper alloys are highly resistant to corrosion. The best (traditional) example of copper alloy is bronze (made by mixing tin and brass). Following are the major alloys of copper − Brass Bronze Auricupride Chinese silver Corinthian bronze Electrum, Green gold Grey gold Niello Panchaloha Rose, red, and pink gold Spangold Shibuichi Tibetan silver White gold Compounds of Copper Following are the major compounds of the copper − Cupric acetate - Cu(CH3COO)2 Copper(I) oxide - Cu2O Copper(II) oxide - CuO Copper(II) chloride - CuCl2 Dicopper chloride trihydroxide - Cu2(OH)3Cl Copper(I) chloride - CuCl Copper(II) nitrate - Cu(NO3)2 Copper Cyanide - CuCN Uses of Copper Copper is largely used in making electric wires. Copper is used in electric motors. Copper is used in roofing, plumbing, and in many other industries. Copper paint is used in painting boats and many other materials. Many of the home appliances are made up of either pure copper or its alloys. Chemistry - Silver Introduction Silver is a soft, lustrous transition, and white metal. Silver has the highest electrical and thermal conductivity; and, it has also the highest reflectivity of any metal. Silver The symbol of silver is ‘Ag’ and atomic number is ’47.’ Salient Features of Silver Silver is a precious metal used since long time by human beings. Silver is an element of group 11 of the periodic table. Silver has an excellent white metallic luster commonly used in a high polish. As silver has no color; therefore, it has high reflectivity (of light). Silver has very high electrical and thermal conductivity. Its electric conductivity is the highest – higher than copper. Among all the metals, silver also has the lowest contact resistance. Occurrence of Silver The metal silver is usually found in the Earth's crust in the pure form. Silver also found as an alloy with the gold and some other metals. Silver is also found in some minerals, such as argentite and chlorargyrite. Silver is largely produced as a byproduct of gold, copper, zinc, lead, etc. Alloys of Silver Following are the major alloys of silver − Argentium sterling silver Britannia silver Doré bullion Electrum Goloid Platinum sterling Sterling silver Tibetan silver Compounds of Silver Following are the major compound of silver − Silver chloride - AgCl Silver iodide - Agl Silver bromide - AgBr Silver oxide - Ag2O Silver sulfide - Ag2S Silver fluoride - AgF Silver cyanide - AgCN Silver carbonate - Ag2CO3 Silver acetate - AgC2H3O2 Silver sulfate - Ag2SO4 Silver chromate - Ag2CrO4 Silver oxalate - Ag2C2O4 Silver chlorate - AgClO3 Uses of Silver Following are the major uses of silver − From the ancient period, silver is being used in making coins. Silver is also used in making ornaments. Many of the home pots and other utensils were also used to be made by silver. Silver has also medicinal use, as it is used as an antibiotic coating in medical devices. Because of having very high electric conductivity, silver is commonly used in some electronic devices. Besides, silver has many other uses, such as in photography, in chemical equipment, nanoparticles, etc. Chemistry - Gold Introduction Gold is a bright, reddish yellow, soft, dense, malleable, and ductile metal naturally found in the earth’s crust. The symbol of gold is ‘Au’ and atomic number is ‘79.’ Gold Gold is (chemically) a transition metal and belongs to group 11 of the periodic table. Salient Features of Gold Gold, which remains in a solid state under standard conditions, is the least reactive element. Gold is resistant to most of the acids. Gold does dissolve in aqua regia; aqua regia is a mixture of nitric acid and hydrochloric acid. However, gold is insoluble in nitric acid. Gold usually dissolves in alkaline solutions of cyanide. Cyanide solutions are commonly used in mining and electroplating. Gold also dissolves in mercury and forms ‘amalgam alloys.’ Gold does not react with oxygen at any temperature. Occurrence of Gold Gold commonly occurs as a free element i.e. in the natural form. Gold occurs as nuggets or else found in in rocks, grains, in veins, and in some other alluvial deposits. Gold also occurs in a solid solution forms with the native element such as silver (as electrum). At some places, gold also naturally alloyed with copper and palladium. Alloys of Gold Following are the major alloys of gold − Colored gold Crown gold Electrum Rose gold Tumbaga White gold Compounds of Gold Following are the major compounds of the gold − Gold (III) chloride - AuCl3 Gold (I) chloride - AuCl Cyanide - CN Chloroauric acid - HAuCl4 Gold (III) oxide - Au2O3 Gold bromide - AuBr Aqua regia - HNO3+3HCl Gold bromide - AuBr3 Gold (III) hydroxide - AuH3O3 Gold fluoride - AuF3 Gold (V) fluoride - AuF5 Gold sulfide - Au2S Fulminating gold Gold salts Gold heptafluoride Uses of Gold Gold is one of the oldest elements that human being have been using for thousands of years. As it is highly precious and provides a beautiful look, hence it is characteristically used in making ornaments. As per the recent trend (of the world), about 50% gold is used in making jewelry, 40% used in investments, and remaining 10% is used in industry. Chemistry - Platinum Introduction Platinum is a malleable, ductile, dense, and highly unreactive chemical element. The symbol of platinum is ‘Pt’ and its atomic number is ‘78.’ Platinum The name of platinum is derived from a Spanish term i.e. ‘platina,’ which means "little silver." Platinum is the most precious and the rarest metal (element) on the earth. Salient Features of Platinum Following are the important features of the platinum − Platinum is a silver white metal. Platinum is an element of group 10 of the periodic table. Platinum is one of the rarest elements in the crust of the earth. Platinum is one of the least reactive elements. Platinum has six natural isotopes. Platinum is one of the most highly valuable and precious metals. Platinum is characteristically resists corrosion in all conditions. Because of this reason, it is considered as noble metal. Platinum is normally insoluble in nitric and hydrochloric acid, but dissolves in hot aqua regia. After dissolving into the hot aqua regia, platinum gives aqueous chloroplatinic acid (see the image given below). Platinum Component Occurrence of Platinum Platinum is commonly found as the native (natural) platinum and as alloy with the other platinum-group. Platinum usually occurs in the ores of nickel and copper. Platinum also occurs naturally in the alluvial sands (commonly found in rivers). Platinum occurs with the concentration of only (about) 0.005 ppm in the Earth's crust. Alloys of Platinum Platinum-iridium is one of the most significant alloys of platinum. Compounds of Platinum Following are the major compounds of platinum − Platinum (II) chloride - Pt Cl2 Platinum (IV) chloride - PtCl4 Adam’s catalyst - PtO2 Platinum hexafluoride - PtF6 Potassium tetrachloropla - K2PtCl4 Krogmann’s salt - K2Pt(CN)4Br Chloroplatinic acid - H2PtCl6 Sodium hexachloropl - Na2PtCl6 Aqua regia - HNO3+3HCl Satraplatin Nedaplatin Picoplatin Uses of Platinum Platinum is used largely for vehicle emissions control devices. Platinum is used in petroleum refining and many other chemical productions. Platinum is used in electronic devices, such as in hard disk (drives). Platinum is also used in jewelry. Apart from all these usages, platinum is also used in medicine (anti-cancer drugs), glassmaking equipment, electrodes, turbine engines, investment, etc. Chemistry - Zinc Introduction In the periodic table, zinc is the first element of group 12. The symbol of zinc is ‘Zn’ and the atomic number is ‘30.’ In terms of availability, zinc is the 24th most abundant element found in the Earth's crust and it has five stable isotopes. Zinc The most common zinc ore is sphalerite (zinc blende), which is a zinc sulfide mineral. Andreas Sigismund Marggraf, the German chemist, first discovered the pure metallic zinc in 1746. Interestingly, alchemists burned zinc in the air and form something different thing and they named that "philosopher's wool" or "white snow." Salient Features of Zinc Zinc’s color is bluish-white and it is lustrous and diamagnetic metal. Zinc metal is normally hard and brittle; however, at when the temperature increases from 1000C, it becomes malleable. When temperature increases 2100C, then the zinc metal again becomes brittle and can be pulverized easily by beating. Zinc is a conductor of electricity. Occurrence of Zinc Zinc usually found in association with some other base metals such as copper and lead. Sphalerite is a form of zinc sulfide and it is the most heavily mined ore. Sphalerite contains about 60 to 62% zinc. Alloys of Zinc Following are the major alloys of zinc − Brass Nickel silver German silver Compounds of Zinc Following are the major compounds of zinc − Zinc oxide - ZnO Zinc sulfide - ZnS Zinc halides - ZnF2 Zinc nitrate - Zn(NO3)2 Zinc chlorate - Zn(ClO3)2 Zinc sulfate - ZnSO4 Zinc phosphate - Zn3(PO4)2 Zinc molybdate - ZnMoO4 Zinc chromate - ZnCrO4 Zinc arsenite - Zn(AsO2)2 Zinc acetate - Zn(O2CCH3)2 Uses of Zinc Zinc is one of the most important elements for the public health. Zinc is largely used as an anti-corrosion agent and coating of iron and steel materials. Zinc is commonly used as the anode or fuel of the zinc-air battery. Zinc oxide is extensively used as a white pigment (see the image given below) in paints. Zinc Component Zinc oxide is also used as a catalyst in manufacturing rubber. Zinc is an essentially required element for our health; it is normally used as supplementary materials in the forms as zinc oxide, zinc acetate, or zinc gluconate. Zinc is normally antioxidant material. Zinc deficiency in human body may cause major depressive disorder. After the bodily injury, zinc is used to speed up the healing process. Zinc pyrithione is commonly used in shampoos to prevent the dandruff. Chelated zinc is usually used in toothpastes and mouthwashes (liquid), as it prevents the bad breath. Zinc also protects skin from sunburn, therefore, it is used in body lotions. Chemistry - Mercury Introduction Mercury is a chemical element, which usually known as ‘quicksilver.’ Formerly, mercury was named as ‘hydrargyrum.’ The symbol of mercury is ‘Hg’ and atomic number is ‘80.’ Mercury The red pigment vermilion is extracted by grinding either natural cinnabar or synthetic mercuric sulfide. Salient Features of Mercury Mercury is a heavy and silvery-white metal. Mercury usually available in liquid state; in normal condition, it is only the few metallic element that remains in liquid state at room temperature. Mercury is the poor conductor of heat, but it is a good conductor of the electricity. The freezing point of mercury is −38.830C and the boiling point is 356.730C. Mercury poisoning caused because of the ingesting any form of mercury. It is also caused by inhalation of mercury vapor. Mercury dissolves many metals including gold and silver to form amalgams. Occurrence of Mercury Mercury is one of the rarest element in the earth’s crust. The richest mercury ores carry about 2.5 percent mercury (in terms of mass). Mercury is found either as a native (natural) element) or in corderoite, cinnabar, livingstonite, etc. minerals. Mercury is found the region of young mountain belt; the belt that keep forcing the denser rocks to the crust of the earth. For example, volcanic region or even hot spring regions. Alloys of Mercury Amalgam is the major alloy of mercury. Compounds of Mercury Following are the major compounds of Mercury − Mercury (II) chloride - HgCl2 Mercury (II) oxide - HgO Mercury sulfide - HgS Mercury (I) – chloride - Hg2Cl2 Dimethylmer - C2H6Hg Mercury (II) nitrate - Hg(NO3)2 Mercury (II) acetate - C4H6O4Hg Mercury (II) sulfate - HgSO4 Mercury (I) iodide - Hg2I2 Mercury selenide - HgSe Mercury (II) fulminate - Hg(CNO)2 Mercury (II) bromide - HgBr2 Mercury (II) iodide - HgI2 Mercury (I) oxide - Hg2O Mercury (I) fluoride - Hg2F2 Mercuric amidochloride - ClH2HgN Diethylmercury - C4H10Hg Sodium amalgam Nitromersol Uses of Mercury Mercury is largely used in chemical industries. Mercury is used in electrical and electronic application. Mercury is used in the thermometers that we use to measure the temperature. Mercury along with its compounds are commonly used in various medicines. Chemistry - Plutonium Introduction Plutonium is basically an actinide metal and it appears like silvery-gray. The element, which atomic number is ranging between 89 and 103, is known as actinide element. The symbol of plutonium is ‘Pu’ and atomic number is ‘94.’ Plutonium Plutonium normally possesses six allotropes. Plutonium is named after ‘Pluto.’ Plutonium was first discovered in 1940, by a group of scientists namely Glenn T. Seaborg, Joseph W. Kennedy, Edwin M. McMillan and Arthur C. Wahl. Salient Features of Plutonium Plutonium is a radioactive chemical element. Plutonium when exposed to air, it gets tarnished and when it oxidized, it forms a dull coating. Plutonium reacts with many elements including halogens, nitrogen, carbon, silicon, and hydrogen. Because of fission process, neutrons get released and convert uranium-238 nuclei into plutonium-239. Plutonium-239 and plutonium-241 both are fissile, and hence, they can sustain a nuclear chain reaction. It is very well applicable in nuclear weapons and nuclear reactors. The melting point of plutonium is 640 0C and its boiling point is 3,228 0C. The release of helium nucleus (a high-energy) is the most common form of radioactive decay for the plutonium. Occurrence of Plutonium The plutonium naturally found only in trace amounts within the uranium deposits. Plutonium is also extracted by burning the uranium (while developing nuclear energy). Alloys of Plutonium Following are the major alloys of plutonium − Plutonium–gallium is one of the important alloys of plutonium as well as of gallium. Plutonium–gallium is used in the nuclear weapon pits. Plutonium–gallium has the property of very low thermal expansion. Some other alloys of plutonium are − Plutonium–aluminum Plutonium–gallium–cobalt Plutonium–zirconium Plutonium–cerium Plutonium–uranium Plutonium–uranium–titanium Thorium–uranium–plutonium Compounds of Plutonium Plutonium (IV) oxide - PuO2 Plutonium (III) chloride - PuCl3 Plutonium tetrafluoride - PuF4 Plutonium (III) fluoride Plutonium hexafluoride Plutonium hydride Plutonium carbide Plutonium borides Uses of Plutonium The isotope plutonium-239 is one of the significant elements in developing the nuclear weapons. Plutonium is used as a fuel in the nuclear power plants. Chemistry - Uranium Introduction Uranium is the metal of the actinide series of the periodic table. The symbol of uranium is ‘U’ and atomic number is ’92.’ Uranium In 1789, Martin Heinrich Klaproth had discovered the element uranium and named it after the name of Uranus. Salient Features of Uranium Uranium is a silvery-white metal. A uranium atom has 92 electrons as well as 92 protons, of which 6 are valence electrons. Because of having unstable isotopes, uranium is a weak radioactive element. Uranium-238 is the most common isotope of uranium. Uranium occurs naturally in very low concentrations i.e. a few parts per million in rock, soil, and water. Uranium decays gradually (slowly) by emitting its alpha particle. Uranium has poor electric conductivity (so poor conductor of electricity). Uranium is malleable, ductile, and marginally paramagnetic Occurrence of Uranium Uranium is (naturally) found as uranium-238, uranium-235, and uranium-234. The half-life of uranium-238 is about 4.47 billion years almost the age of the Earth and the half-life of uranium-235 is about 704 million years. Alloys of Uranium Following are the major alloys of Uranium − Staballoy Uranium hydride Compounds of Uranium Following are the major compounds of Uranium − Uranium nitride - U2N3 Uranium pentafluoride - UF5 Uranium carbide - UC Uranyl fluoride - UO2F2 Uranium dioxide - UO2 Uranium hexafluoride - UF6 Triuranium oxtoxide - U3O8 Uranium tetrafluoride - UF4 Uranium trioxide - UO3 Uranium tetrachloride - Ucl4 Uranyl nitrate - UO2(NO3)2 Uranyl Uraninite Ammonium diuranate Hexafluoride Uranium hexachloride Uranium (III) iodide Uranyl acetate Uses of Uranium Uranium is used as power source in nuclear submarines (especially by military). Uranium is used in making nuclear weapons. Uranium is also used as ballasts for ships. Chemistry - Lead Introduction Lead is a heavy chemical element (metal) i.e. it has high density. The symbol of lead is ‘Pb’ and atomic number is ‘82.’ Lead Lead has tendency to bond itself; likewise, it can form chains, bonds, rings, and polyhedral structures. Salient Features of Lead Lead is soft and malleable metal; it has relatively low melting point. Lead is relatively unreactive element and it has tendency to form covenant bond. When lead is cut, it appears bluish-white tint. While burning, lead gives a bluish-white flame (see the image given below). Lead Component Compounds of lead are typically found in the +2 oxidation state. Occurrence of Lead Lead is known to the prehistoric people of Western Asia. Lead is found in the earth’s crust; it is rarely found deep of the earth. Lead is usually found in combination with sulfur. Galena is the main lead-bearing mineral, mostly found with zinc ores. Alloys of Lead Following are the major alloys of lead − Molybdochalkos (copper) Solder (tin) Terne (tin) Compounds of Lead Following are the major compounds of lead − Lead monoxide - PbO Lead dioxide - PbO2 Uses of Lead Lead has been used in making bullets for hundreds of years. Lead is commonly used as a protective sheath for the underwater cables (only because it has the property of corrosion resistance). Lead sheets are also used as architectural metals especially in roofing material. Lead is also used in acid batteries. Lead compounds are commonly as coloring agents and semiconductors. Lead compounds are also used in plastic, candles, glass, etc. Lead is commonly used in the polyvinyl chloride (i.e. used in coating of electrical cords). Pre-caution Presence of lead (in excessive quality) in the body may cause severe damage to the brain and kidneys; it may even cause death lastly. Chemistry - Thorium Introduction Thorium is one of the radioactive actinide metals that occur naturally in large quantities. The symbol of thorium is ‘Th’ and atomic number is ’90.’ Thorium In 1829, a Norwegian mineralogist Morten Thrane Esmark, first discovered thorium. Jöns Jacob Berzelius, the Swedish chemist, identified and named it ‘thorium’ after the name of ‘Thor’, the Norse god of thunder. Salient Features of Thorium Thorium is paramagnetic and soft radioactive actinide metal. Thorium metal’s color is silvery; when it exposed to air, it tarnishes black and form dioxide. All isotopes of thorium are unstable and it is a weak radioactive element. Among all the significant radioactive elements, the half-life of thorium is the longest, i.e. about 14.05 billion years. The melting point of thorium is about 17500C. Occurrence of Thorium Thorium is primordial element that exists existed in its current form since before the Earth was formed. Thorium, found in the earth’s crust, is refined from the monazite sands. Monazite that occurs in large amounts across the world is the most important source of thorium. Alloys of Thorium Mag-Thor and thorium-aluminum are the most significant alloys of thorium, Magnesium, and aluminum. Compounds of Thorium Following are the major compounds of Thorium − Thorium dioxide - ThO2 Thorium (IV) sulfide - ThS2 Thorium (IV) iodide - ThI4 Thorium tetrafluoride - ThF4 Thorium (IV chloride - ThCl4 Thorium (IV) carbide - ThC Some others are − Thorite Thorium (IV) nitrate Thorium (IV) orthosilicate Uses of Thorium Thorium is normally used in gas tungsten arc welding (GTAW) because it (thorium) increases the high-temperature strength of tungsten electrodes and accordingly improve arc stability. In electronic equipment, the application of thorium coating on tungsten wire, increases the electron emission of heated cathodes. In chemical industry, the dioxide of thorium namely ‘thoria’ is commonly used. Chemistry - Hydrogen Introduction In the periodic table, hydrogen is the lightest element, its atomic weight is merely 1.008. The symbol of hydrogen is ‘H’ and the atomic number is ‘1.’ Hydrogen In the early 16th century, hydrogen gas was first artificially produced by the reaction of acids and metals. Henry Cavendish first recognized the hydrogen gas a discrete substance during the period of 1766-81, as it produces water when it is burned. Salient Features of Hydrogen In their plasma state, the non-remnant stars are primarily composed of hydrogen. At standard temperature and pressure, hydrogen appears colorless, tasteless, odorless, nonmetallic, non-toxic, and highly combustible diatomic gas. The molecular formula of hydrogen is H2. On the earth, hydrogen exists in molecular forms, for example, water or other organic compounds. Hydrogen also plays an important role in acid–base reactions. Hydrogen gas is highly flammable in the air. Pure hydrogen-oxygen flames radiate ultraviolet light; further, with high oxygen mix are nearly invisible to the naked eye. Hydrogen can react with almost every oxidizing element. At room temperature, Hydrogen normally reacts spontaneously and viciously with chlorine and fluorine and forms the corresponding hydrogen halides. Occurrence of Hydrogen Consisting roughly about 75 percent of all baryonic mass, hydrogen is the most abundantly found chemical subsistence in the universe. Throughout the universe, hydrogen is typically found in the atomic and plasma states; however, the properties quite different from those of the molecular hydrogen. On the earth, hydrogen exists as the diatomic gas, i.e. H2. Because of having light weight, hydrogen easily escapes from the earth’s atmosphere. Hydrogen is the third most abundant element found on the Earth's surface, but largely found in form of hydrocarbons and water. Compounds of Hydrogen Following are the major compounds of hydrogen − Water - H2O Ammonia - NH3 Hydrogen chloride - HCl Hydrogen fluoride - HF Hydrogen sulfide - H2S Methane - CH4 Hydroxide - OH- Hydrogen bromide - HBr Hydrogen iodide - HI Hydrogen cyanide - HCN Phosphine - PH3 Hydrogen selenide - H2Se Methanol - CH3OH Lithium hydride - LiH Bicarbonate - HCO3 Hydrogen telluride - H2Te Liquid hydrogen - H2 Cyanide - CN Calcium hydride - CaH2 Heavy water - D2O Diborane - B2H6 Sodium hydride - NaH Potassium hydride - KH Uses of Hydrogen The largest amount of H2 is used in the processing of fossil fuels as well as in the production of ammonia. Hydrogen (H2) is extensively used in the petroleum and chemical industries. H2 is typically used as a hydrogenating agent, especially in increasing the saturation level of unsaturated fats and oils. H2 is also used as a shielding gas in welding procedures, such as atomic hydrogen welding, etc. Chemistry - Helium Introduction Helium is the second lightest (after hydrogen) and second most abundant element in the universe. The symbol of Helium is ‘He’ and atomic number is ‘2.’ Helium In the periodic table, Helium is the first in the noble gas group. Helium is named after the name of the Greek god of the Sun, ‘Helios.’ Salient Features of Helium Helium is a colorless, odorless, tasteless, inert, non-toxic, and monatomic gas. The boiling point (-268.90C) of helium is the lowest among all the elements. Helium is typically composed of two electrons in atomic orbitals and surrounded by a nucleus. Occurrence of Helium Most helium found in the universe belong to helium-4, and it is believed to have been formed during the Big Bang. Major share of new helium is typically being created by nuclear fusion of hydrogen in stars including the Sun. Though there is continuous creation of new helium; In the earth’s crust, helium is characteristically found in large amounts in the minerals of uranium and thorium. Compounds of Helium Following are the major compounds of helium − Disodium helide - Na2He Cristobalite He II (Silicates) - SiO2He Dihelium arsenolite - As4O6•2He Isotopes of Helium There are about nine known isotopes of helium, but following two are the most stable isotopes − Helium-3 and Helium-4 Uses of Helium Because of having low density, low boiling point, low solubility, high thermal conductivity, helium is widely used element; the most popular example is – use of helium in balloon. Helium is also used as a protective gas in growing silicon and germanium crystals. Helium is used in supersonic wind tunnels. Helium is also applied as a shielding gas in an arc welding processes. Chemistry - Oxygen Introduction Oxygen is the member of group 16 on the periodic table; however, most of the time, it is treated differently from its group. The symbol of oxygen is ‘O’ and atomic number is ‘8.’ Oxygen Oxygen has about nine allotropes and the most common allotrope is diatomic oxygen (i.e. O2). Other important allotrope is Ozone i.e. O3. Oxygen, first time, was noticed by Swedish pharmacist Carl Wilhelm Scheele. The word "chalcogen" is derived from a Greek word “khalkόs,” which means “copper” and the Latin-Greek word “Genēs,” which means born or produced. Oxygen is a highly reactive gas (or nonmetallic element); hence, it is an oxidizing agent that readily forms oxides with most of the elements and compounds. Oxygen has six valence electrons. The melting point of oxygen is -218.80C and the boiling point is -1830C. Occurrence of Oxygen With about 20.8 percent share (in total earth’s atmospheric constituents), oxygen is the second ranked element of the earth’s atmosphere. Oxygen occurs almost in sphere of the earth namely atmosphere, hydrosphere, and lithosphere. Oxygen occurs as constituent copper ores. A human body contains about 65 percent oxygen. By mass, almost half of the earth’s crust is composed of oxygen (i.e. its oxides). By mass, oxygen is the third-most abundant element that found in the universe; the first and second are hydrogen and helium accordingly. Oxygen (i.e. O2) is a colorless and odorless diatomic gas. Compounds of Oxygen Following are the major compounds of oxygen − Oxide Peroxide Carbon dioxide - CO2 Hydroxide - OH- Ozone - O3 Mercury (II) oxide - HgO Chlorate - ClO3 Aluminum oxide - Al2O3 Carbon monoxide - CO Hypochlorite - ClO- Silicon dioxide - SiO2 Hypofluorous acid - HOF Sodium peroxide - Na2O2 Potassium chlorate - KClO3 Oxygen difluoride - OF2 Sodium oxide - Na2O Uses of Oxygen Oxygen (O2) is the most essential requirements for the respiration, without it, life cannot be imagined. Oxygen is used in medicine. Oxygen therapy is typically used to treat some diseases, such as, emphysema, pneumonia, some heart disorders, etc. Some of the underwater activities, such as scuba diving, submarines, etc. also use artificial oxygen. Artificial Oxygen. Quetta Library Thanks. for
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